Recent advance in high-pressure solid-state metathesis reactions

Lei Li; Zhang Leilei

doi:10.1016/j.mre.2017.12.003

Volume 3 Issue 3

May 2018

Turn off MathJax

Article Contents

Article Navigation > Matter and Radiation at Extremes > 2018 > 3(3):

Lei Li, Zhang Leilei. Recent advance in high-pressure solid-state metathesis reactions[J]. Matter and Radiation at Extremes, 2018, 3(3). doi: 10.1016/j.mre.2017.12.003

Citation:

Lei Li, Zhang Leilei. Recent advance in high-pressure solid-state metathesis reactions[J]. Matter and Radiation at Extremes, 2018, 3(3). doi: 10.1016/j.mre.2017.12.003

Lei Li, Zhang Leilei. Recent advance in high-pressure solid-state metathesis reactions[J]. Matter and Radiation at Extremes, 2018, 3(3). doi: 10.1016/j.mre.2017.12.003

Citation:

Lei Li, Zhang Leilei. Recent advance in high-pressure solid-state metathesis reactions[J]. Matter and Radiation at Extremes, 2018, 3(3). doi: 10.1016/j.mre.2017.12.003

PDF( 3227 KB)

Recent advance in high-pressure solid-state metathesis reactions

doi: 10.1016/j.mre.2017.12.003

Lei Li^,,
Zhang Leilei

Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China

More Information

Corresponding author: *Corresponding author. E-mail address: lei@scu.edu.cn (L. Lei).
Received Date: 2017-04-23
Accepted Date: 2017-12-26
Publish Date: 2018-05-15

Abstract

Abstract

High-pressure solid-state metathesis (HPSSM) reaction is an effective route to novel metal nitrides. A recent advance in HPSSM reactions is presented for a number of examples, including 3d transition metal nitrides (ε-Fe₃N, ε-Fe_3−xCo_xN, CrN, and Co₄N_x), 4d transition metal nitrides (MoN_x), and 5d transition metal nitrides (Re₃N, WN_x). Thermodynamic investigations based on density functional theory (DFT) calculations on several typical HPSSM reactions between metal oxides and boron nitride indicate that the pressure could reduce the reaction enthalpy ΔH. High-pressure confining environment thermodynamically favors an ion-exchange process between metal atom and boron atom, and successfully results in the formation of well-crystalized metal nitrides with potential applications.
- High-pressure,
- Solid-state metathesis reaction,
- Metal nitrides

FullText(HTML)

References(28)

References

[1]	E. Gregoryanz, C. Sanloup, M. Somayazulu, J. Badro, G. Fiquet, et al., Synthesis and characterization of a binary noble metal nitride, Nat. Mater. 3 (5) (2004) 294–297.10.1038/nmat1115
[2]	J.C. Crowhurst, A.F. Goncharov, B. Sadigh, C.L. Evans, P.G. Morrall, et al., Synthesis and characterization of the nitrides of platinum and iridium, Science 311 (5765) (2006) 1275–1278.10.1126/science.1121813
[3]	A.F. Young, C. Sanloup, E. Gregoryanz, S. Scandolo, R.J. Hemley, et al., Synthesis of novel transition metal nitrides IrN2 and OsN2, Phys. Rev. Lett. 96 (15) (2006) 155501.10.1103/physrevlett.96.155501
[4]	M. Chhowalla, H.E. Unalan, 2005. Thin films of hard cubic Zr3N4 stabilized by stress. Nat. Mater. 4 (4), 317–322.10.1038/nmat1338
[5]	A. Zerr, G. Miehe, R. Riedel, Synthesis of cubic zirconium and hafnium nitride having Th3P4 structure, Nat. Mater. 2 (3) (2003) 185–189.10.1038/nmat836
[6]	A. Friedrich, B. Winkler, L. Bayarjargal, W. Morgenroth, E.A. Juarez-Arellano, et al., Novel rhenium nitrides, Phys. Rev. Lett. 105 (8) (2010) 085504.10.1103/physrevlett.105.085504
[7]	aJ.L. O'Loughlin, C.H. Wallace, M.S. Knox, R.B. Kaner, Rapid solid-state synthesis of tantalum, chromium, and molybdenum nitrides, Inorg. Chem. 40 (10) (2001) 2240–2245;10.1021/ic001265h
[8]	aI.P. Parkin, A.T. Nartowski, Fast metathesis routes to tungsten and molybdenum carbides, J. Mater. Sci. Lett. 18 (4) (1999) 267–268;10.1023/a:1006650332712
[9]	aH. Zhao, M. Lei, X. Yang, J. Jian, X. Chen, Route to GaN and VN assisted by carbothermal reduction process, J. Am. Chem. Soc. 127 (45) (2005) 15722–15723;10.1021/ja055877i
[10]	C.H. Wallace, S.H. Kim, G.A. Rose, L. Rao, J.R. Heath, et al., Solid-state metathesis reactions under pressure: a rapid route to crystalline gallium nitride, Appl. Phys. Lett. 72 (5) (1998) 2.10.1063/1.120818
[11]	L. Lei, D. He, Synthesis of GaN crystals through solid-state metathesis reaction under high pressure, Cryst. Growth Des. 9 (3) (2009) 1264–1266.10.1021/cg801017h
[12]	W. Yin, L. Lei, X. Jiang, P. Liu, F. Liu, et al., High pressure synthesis and properties studies on spherical bulk ε – Fe3N, High Pres. Res. 34 (3) (2014) 317–326.10.1080/08957959.2014.944910
[13]	X. Jiang, L. Lei, Q. Hu, Z.C. Feng, D.W. He, High-pressure Raman spectroscopy of Re3N crystals. Solid State Commun. 201 (2015) 107–110.10.1016/j.ssc.2014.10.031
[14]	S. Wang, X. Yu, J. Zhang, L. Wang, K. Leinenweber, et al., Synthesis, hardness, and electronic properties of stoichiometric VN and CrN, Cryst. Growth Des. 16 (1) (2015) 351–358.10.1021/acs.cgd.5b01312
[15]	M. Chen, S. Wang, J. Zhang, D. He, Y. Zhao, Synthesis of stoichiometric and bulk CrN through a solid-state ion-exchange reaction, Chem. A Eur. J. 18 (48) (2012) 15459–15463.10.1002/chem.201202197
[16]	S. Wang, X. Yu, Z. Lin, R. Zhang, D. He, et al., Synthesis, crystal structure, and elastic properties of novel tungsten nitrides, Chem. Mater. 24 (15) (2012) 3023–3028.10.1021/cm301516w
[17]	S. Wang, H. Ge, S. Sun, J. Zhang, F. Liu, et al., A new molybdenum nitride catalyst with rhombohedral MoS2 structure for hydrogenation applications, J. Am. Chem. Soc. 137 (2015) 4815–4822.10.1021/jacs.5b01446
[18]	S. Gao, L. Lei, Q. Hu, L.M. Fang, X.L. Wang, et al., High-pressure solid-state metathesis synthesis of ternary iron-based metal nitrides, Chin. J. High Press. Phys. 30 (4) (2016) 265–270.
[19]	L. Lei, W. Yin, X. Jiang, S. Lin, D. He, et al., Synthetic route to metal nitrides: high-pressure solid-state metathesis reaction, Inorg. Chem. 52 (23) (2013) 13356–13362.10.1021/ic4014834
[20]	H. Ma, D. He, L. Lei, S. Wang, Y. Chen, et al., GaN crystals prepared through solid-state metathesis reaction from NaGaO2 and BN under high pressure and high temperature, J. Alloy. Comp. 509 (7) (2011) L124–L127.10.1016/j.jallcom.2010.12.087
[21]	H. Ohfuji, M. Yamamoto, EDS quantification of light elements using osmium surface coating, J. Mineral. Petrol. Sci. 110 (4) (2015) 189–195.10.2465/jmps.141126
[22]	Y. Zhou, T. Irifune, H. Ohfuji, T. Shinmei, W. Du, Stability region of K0.2Na0.8AlSi3O8 hollandite at 22 GPa and 2273 K, Phys. Chem. Miner. 44 (1) (2017) 33–42.10.1007/s00269-016-0834-5
[23]	Y. Kojima, H. Ohfuji, Structure and stability of carbon nitride under high pressure and high temperature up to 125 GPa and 3000 K, Diam. Relat. Mater. 39 (2013) 1–7.10.1016/j.diamond.2013.07.006
[24]	A.B. Belonoshko, R. Ahuja, B. Johansson, Stability of the body-centred-cubic phase of iron in the Earth's inner core, Nature 424 (6952) (2003) 1032–1034.10.1038/nature01954
[25]	M. Chen, S. Wang, J. Zhang, D. He, Y. Zhao, Synthesis of stoichiometric and bulk CrN through a solid-state ion-exchange reaction, Chem. A Eur. J. 18 (48) (2012) 15459–15463.10.1002/chem.201202197
[26]	S. Wang, X. Yu, J. Zhang, M. Chen, J. Zhu, et al., Experimental invalidation of phase-transition-induced elastic softening in CrN, Phys. Rev. B 86 (6) (2012) 064111.10.1103/physrevb.86.064111
[27]	B. Alling, T. Marten, I.A. Abrikosov, Questionable collapse of the bulk modulus in CrN, Nat. Mater. 9 (4) (2010) 283–284.10.1038/nmat2722
[28]	X.J. Chen, V.V. Struzhkin, Z. Wu, M. Somayazulu, J. Qian, et al., Hard superconducting nitrides, Proc. Natl. Acad. Sci. U. S. A. 102 (9) (2005) 3198–3201.10.1073/pnas.0500174102