Recent progress on high-pressure and high-temperature studies of fullerenes and related materials

Pei Cuiying; Wang Lin

doi:10.1063/1.5086310

Volume 4 Issue 2

Mar. 2019

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Pei Cuiying, Wang Lin. Recent progress on high-pressure and high-temperature studies of fullerenes and related materials[J]. Matter and Radiation at Extremes, 2019, 4(2): 028201. doi: 10.1063/1.5086310

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Pei Cuiying, Wang Lin. Recent progress on high-pressure and high-temperature studies of fullerenes and related materials[J]. Matter and Radiation at Extremes, 2019, 4(2): 028201. doi: 10.1063/1.5086310

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Recent progress on high-pressure and high-temperature studies of fullerenes and related materials

doi: 10.1063/1.5086310

Center for High Pressure Science and Technology Advanced Research (HPSTAR), 1690 Cailun Rd., Pudong District, Shanghai 201203, People’s Republic of China

Received Date: 2018-08-01
Accepted Date: 2018-10-30

Available Online: 2021-04-13

Publish Date: 2019-03-15

Abstract

Abstract

Polymerization of fullerenes is an interesting topic that has been studied for almost three decades. A rich polymeric phase diagram of C₆₀ has been drawn under a variety of pressure P and temperature T conditions. Knowledge of the targeted preparation and structural control of fullerene polymers has become increasingly important because of their utility in producing novel fullerene-based architectures with unusual properties and potential applications. This paper focuses on the polymeric phases of fullerenes and their derivatives under high P and/or high T. First, the polymerization behavior and the various polymeric phases of C₆₀ and C₇₀ under such conditions are briefly reviewed. A summary of the polymerization process of intercalated fullerenes is then presented, and a synthetic strategy for novel structural and functional fullerene polymers is proposed. Finally, on the basis of the results of recent research, a proposal is made for further studies of endohedral fullerenes at high P.

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References(161)

References

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