Thermal equation of state of a natural kyanite up to 8.55 GPa and 1273 K

He Qiang; Liu Xi; Li Baosheng; Deng Liwei; Liu Wei; Wang Liping

doi:10.1016/j.mre.2016.07.003

Volume 1 Issue 5

Sep. 2016

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He Qiang, Liu Xi, Li Baosheng, Deng Liwei, Liu Wei, Wang Liping. Thermal equation of state of a natural kyanite up to 8.55 GPa and 1273 K[J]. Matter and Radiation at Extremes, 2016, 1(5). doi: 10.1016/j.mre.2016.07.003

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He Qiang, Liu Xi, Li Baosheng, Deng Liwei, Liu Wei, Wang Liping. Thermal equation of state of a natural kyanite up to 8.55 GPa and 1273 K[J]. Matter and Radiation at Extremes, 2016, 1(5). doi: 10.1016/j.mre.2016.07.003

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Thermal equation of state of a natural kyanite up to 8.55 GPa and 1273 K

doi: 10.1016/j.mre.2016.07.003

He Qiang^{1, 2, 3},
Liu Xi^{1, 2
,
,},
Li Baosheng⁴,
Deng Liwei⁵,
Liu Wei⁴,
Wang Liping⁶

1.
aKey Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education of China, Beijing 100871, China
2.
bSchool of Earth and Space Sciences, Peking University, Beijing 100871, China
3.
cInstitute of Fluid Physics, China Academy of Engineering Physics, Mianyang 621900, China
4.
dMineral Physics Institute, Stony Brook University, Stony Brook, NY 11794-2100, USA
5.
eInstitute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
6.
fHigh Pressure Science and Engineering Center and Department of Physics and Astronomy, University of Nevada, Las Vegas, NV 89154, USA

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Corresponding author: *Corresponding author. School of Earth and Space Sciences, Peking University, Beijing 100871, China. Fax: +86 10 6275 2996. E-mail address: xi.liu@pku.edu.cn (X. Liu).
Received Date: 2016-05-10
Accepted Date: 2016-07-27
Publish Date: 2016-09-15

Abstract

Abstract

The thermal equation of state of a natural kyanite has been investigated with a DIA-type, cubic-anvil apparatus (SAM85) combined with an energy-dispersive synchrotron X-ray radiation technique up to 8.55 GPa and 1273 K. No phase transition was observed in the studied pressure-temperature (P-T) range. The Le Bail full profile refinement technique was used to derive the unit-cell parameters. By fixing the bulk modulus K₀ as 196 GPa and its pressure derivative K0′ as 4, our P-V (volume)-T data were fitted to the high temperature Birch–Murnaghan equation of state. The obtained parameters for the kyanite are: V₀ = 294.05(9) Å³, α = 2.53(11) × 10⁻⁵ K⁻¹ and (∂K/∂T)_P = −0.021(8) GPa∙K⁻¹. These parameters have been combined with other experimentally-measured thermodynamic data for the relevant phases to calculate the P-T locus of the reaction kyanite = stishovite + corundum. With this thermodynamically constrained phase boundary, previous high-pressure phase equilibrium experimental studies with the multi-anvil press have been evaluated.
- Kyanite,
- X-ray diffraction,
- Thermal equation of state,
- High-pressure and high-temperature,
- Kyanite decomposition,
- Thermodynamic calculation

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References(46)

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